CobaltMaghrebV1, France, Analysis, bibRecord, 000032

(5,10,15,20-Tetraphenylporphyrinato-κ4N)zinc–18-crown-6 (1/1)

Identifieur interne : 000032 ( France/Analysis ); précédent : 000031; suivant : 000033

(5,10,15,20-Tetraphenylporphyrinato-κ4N)zinc–18-crown-6 (1/1)

Auteurs : Zouhour Denden [Tunisie] ; Leila Bel Haj Hassen [Tunisie] ; Mohamed Salah Belkhiria [Tunisie] ; Jean-Claude Daran [France] ; Habib Nasri [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.

RBID : PMC:3793685

Abstract

In the title compound, [Zn(C₄₄H₂₈N₄)]·C₁₂H₂₄O₆, the Zn^II ion lies on an inversion center and the asymmetric unit contains one half of a Zn(TPP) complex (TPP = 5,10,15,20-tetraphenylporphyrin dianion) and one half of a centrosymmetric 18-crown-6 molecule. The Zn(TPP) complex exhibits a nearly planar conformation of the porphyrin core [maximum deviation = 0.106 (2) Å] with an average Zn—N distance of 2.047 (2) Å. The title compound is considered as a one-dimensional polymer along [010], in which the Zn(TPP) moiety is linked to the closest O atoms of two symmetry-related 18-crown-6 molecules with a Zn—O distance of 2.582 (1) Å, completing a distorted octahedral coordination environment of the metal ion. The chains are mainly sustained by weak C—H⋯π interactions. An ethylene group of the 18-crown-6 molecule is disordered over three sites with occupancies of 0.50, 0.25 and 0.25.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793685

DOI: 10.1107/S1600536813018126
PubMed: 24109272
PubMed Central: 3793685

Affiliations:

France, Tunisie

Links to Exploration step

PMC:3793685

Le document en format XML

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Serveur d'exploration sur le cobalt au Maghreb

(5,10,15,20-Tetraphenylporphyrinato-κ4N)zinc–18-crown-6 (1/1)

(5,10,15,20-Tetraphenylporphyrinato-κ4N)zinc–18-crown-6 (1/1)

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

(5,10,15,20-Tetra­phenyl­porphyrinato-κ4N)zinc–18-crown-6 (1/1)

(5,10,15,20-Tetra­phenyl­porphyrinato-κ4N)zinc–18-crown-6 (1/1)

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

(5,10,15,20-Tetraphenylporphyrinato-κ4N)zinc–18-crown-6 (1/1)

(5,10,15,20-Tetraphenylporphyrinato-κ4N)zinc–18-crown-6 (1/1)